Hi,
globally on a switch you could use MAC Lockout. Butr that will lockout the client from all ports and VLANs. (see Access Security Guide, Configuring and Monitoring Port Security, MAC Lockout)
On 3810 you could use MAC-ACLs. But as far as I know, this is available at 2540 and up.. so no choice on your 2530. (described also in Access Security Guide).
Maybe someone else knows a solution for 2530...
---------------------------
Different approach: If you can follow security best practices and use a whitelist approach, you wouldn't need to blacklist. Authenticate users / MAC addresses by using a RADIUS server and send back the VLAN, the user shall be assigned to.
Better security, but of course a lot more effort...
Regards, Jörg