For packet capture tools you can look at:
* AirPcap
* Omnipeek (check http://www.wildpackets.com/products/omnipeek_network_analyzer )
For spectrum analyzers you can look at:
* Fluke AirMagnet Spectrum XT
* Metageek WiSpy
For Site-survey tools you can look at:
* Ekahau
* Fluke AirMagnet Surveyor
To asses an existing WiFi deployment I would look at:
* Signal & noise levels at relevant locations (using site-survey tool)
* Possible non-WiFi interference (using spectrum analyzer)
* AP density for planned use (can it support the number of clients?)
* AP locations (placement in hallways or in rooms etc). How much coverage in overlap is there? How will this impact performance?
* Config:
** Channel distribution + channel widths
** SSID config (security, supported data-rates, number of SSID's, etc)
** VLAN's/IP space (enough DHCP leases to support application? Lease time etc, broadcast filtering yes/no?)
That are just some pointers... there's probably a lot more to more to look at :)