At the Virtual AP level under advanced, you would enable "Station Blacklisting" (the master switch). You would also configure the authentication failure blacklist time, which says how long the user would not be able to associate (Zero would be permanent).

In the Captive Portal Authentication Profile, you would also configure "Max Authentication Failures" which would indicate how many times the user would have to fail authentication before they are blacklisted (zero turns off blacklisting).
