For PXE boot to work, you need to add specific attributes in your DHCP responses so that a client can find the PXE server. So if your PXE server comes with a DHCP server, either configure ip-helper/dhcp-relay to the PXE server or another DHCP sercer, or add the required PXE attributes to your existing server on the switch. It really depends on your preference which is the better option. There is no selective forward/relay for DHCP.