Hi,
with command "show redundancy" you will see your status of redundancy.
Start with this document and then follow next related pages.
With two power supplys and management modules and redundant switch-modules you can build a redundant chassies. Here are more information:Frequently asked questions 5400R
I prefer two switches with VSF (virtual chassies) it works like an switchstack with max two 5400R chassies. You need minimum 10GE for mirrorlink between chassies.